Direct mono-insertion of isocyanides into terminal alkynes catalyzed by rare-earth silylamides.
نویسندگان
چکیده
Rare-earth silylamide complexes, Ln[N(SiMe3)2]3 (Ln = Y, La, Sm, Yb), effectively catalyzed the coupling reaction of isocyanides with both aliphatic and aromatic terminal alkynes under mild conditions.
منابع مشابه
Rhenium- and manganese-catalyzed carbon–carbon bond formation using 1,3-dicarbonyl compounds and alkynes*
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ورودعنوان ژورنال:
- Chemical communications
دوره 5 شماره
صفحات -
تاریخ انتشار 2005